Homology and Reduced homology coincide on non trivial pair. In Hatcher page 118, he says that 


There is a completely analogous long exact sequence of reduced homology groups
    for a pair $(X;A)$ with $A\not = \emptyset$ ; This comes from applying the preceding algebraic machinery
    to the short exact sequence of chain complexes formed by the short exact sequences
    $0\rightarrow C_n(A)\rightarrow C_n(X)\rightarrow C_n(X;A)\rightarrow 0$ in nonnegative dimensions, augmented
    by the short exact sequence $0 \rightarrow\mathbb Z \stackrel{1}{\rightarrow} 
\mathbb Z \rightarrow 0 \rightarrow 0  $
     in dimension $−1$. In particular, $\tilde H_n(X;A)$ is the same as $H_n(X;A)$ for all  $n$, when $A\not = \emptyset$.  


Could someone please explain how to derive the last conclusion which means that 
$\tilde H_0(X,A)\cong H_0(X,A)$. Indeed, for $n>0$ this isomorphism holds by construction of reduced homology.  In reduced homology we have 
$$\cdots\rightarrow C_1(X,A)=C_1(X)/C_1(A)\stackrel{\partial_1}{\rightarrow}C_0(X,A)=C_0(X)/C_0(A)\stackrel{\epsilon}{\rightarrow}\mathbb Z \rightarrow 0$$
so $\tilde H_0(X,A)=\ker \epsilon /Im \partial_1$
while in non reduced homology we have 
$$\cdots\rightarrow C_1(X,A)=C_1(X)/C_1(A)\stackrel{\partial_1}{\rightarrow}C_0(X,A)=C_0(X)/C_0(A)\stackrel{\partial_0}{\rightarrow}  0$$
so $ H_0(X,A)=\ker \partial_0 /Im \partial_1$
why are these two groups isomorphic ?
 A: I know this is a very late answer, but I think there is a basic confusion here, which I don't want to let stand. The other answer is very confusing (at least, to me) and since the result almost trivial once one realizes that the OP's reduced relative sequence is wrong, I think it is worthwhile to write down the simple proof.
Indeed, since $A\subseteq X$, and since the reduced chains for $A$ and $X$ are 
$\cdots \longrightarrow  C_1(A)\longrightarrow C_0(A)\longrightarrow\mathbb{Z}\longrightarrow0\quad$ and $\quad \cdots \longrightarrow  C_1(X)\longrightarrow C_0(X)\longrightarrow\mathbb{Z}\longrightarrow0$
by definition the relative chain is given by
$\cdots \longrightarrow  C_1(X)/C_1(A)\longrightarrow C_0(X)/C_0(A)\longrightarrow\mathbb{Z}/\mathbb{Z}\longrightarrow0=$
$\cdots \longrightarrow  C_1(X)/C_1(A)\longrightarrow C_0(X)/C_0(A)\longrightarrow 0\longrightarrow0$.
But this last chain is exactly the same as the one induced by the unreduced chains
$\cdots \longrightarrow  C_1(A)\longrightarrow C_0(A)\longrightarrow0\quad$ and $\quad \cdots \longrightarrow  C_1(X)\longrightarrow C_0(X)\longrightarrow0$ 
so $H(X,A)$ and $\widetilde H(X,A)$ are the same.
A: The comment I made above misunderstood the problem, and I'm sorry for that...
To see they are the same, notice that $C_0(A)$ is not empty so the mapping $C_0(A)\stackrel{\epsilon}{\rightarrow}\mathbb{Z}$ is already surjective. Therefore $C_0(X,A)\stackrel{\epsilon}{\rightarrow}\mathbb{Z}$ is a zero mapping and its kernel is the same as $\ker \partial_0$.
