Is outer measure a measure? In my text book Lebesgue measure is shown to have countable additivity on disjoint sets, i.e. if $A_k$ is a countable sequence of disjoint measurable sets, then $\mu(\bigcup A_k)=\sum\mu(A_k)$.
Thus Lebesgue measure is a measure with an additional property that the empty set has zero measure.
But for outer measure, my text book never says outer measure is a measure, and it does not say anything if outer measure has countable additivity on disjoint sets. So my question is does outer measure has such countable additivity? If not, is there a counter example?
 A: The following seems to be a perfect match to this question. In the following, $|*|$ denotes a Lebesgue measure, and $|*|_e$ denotes an outer measure. The outer measure does not satisfy the countable additivity on disjoint sets because of the existence of non-measurable sets. As a result, outer measure is not a measure.

A: You need to be careful about whether you're talking about measurable sets or any sets at all! There's confusion about this already in your first sentence 

Lebesgue measure is shown to have countable additivity on disjoint
  sets, i.e. if $A_k$ is a countable sequence of disjoint measurable
  sets...;

you need to add the word "measurable" to the first clause.
You ask whether outer measure is countably additive, and precisely because of this confusion I'm not sure whether you're asking about additivity for any disjoint sets or just for measurable sets. The answer to your question is yes or no, depending. Outer measure is countably additive on measurable sets. It is not countably additive on sets in general.
You ask about a counterexample. It's not possible to give a simple example of non-additivity in general. Because the example has to involve non-measurable sets, and even proving that a non-measurable set exists is not trivial...
