We have to take .care of the fact that
(a) more than one ball can go into a box
(b) arrangements through stars and bars are not equi-probable.
(c) probabilities (including box n) must sum to 1.
I believe we shall have to apply PIE, as illustrated below for n = 6, k = 10
Let $m_k$ denote the # of ways k boxes can be filled. Applying PIE, we get
$m_1 = {6\choose 1}\cdot 1^{10} = 6$
$m_2 = {6\choose 2}\cdot [2^{10} - {2\choose 1}\cdot1^{10}] = 15,330$
$m_3 ={6\choose 3}\cdot [3^{10} - {3\choose 2}\cdot2^{10} + {3\choose 1}\cdot 1^{10}] = 1119600$
Proceeding similarly,
$m_4 = 12277800$
$m_5 = 30618000$
$m_6$ = 16435440
Divide by 6^10 for the probabilities, which will sum to 1, as they must.
You can now generalise for $P[E_{k,m,n}]$
Edit:
Oh, comment gives boxes as indistinguishable ! Shall have to rethink !
Edit 2:
In effect, there are n targets at which you are throwing k missiles which always hit some target or other. This makes the targets distinct, which is what I took in my answer