Induction and Pascal's Rule
$$
\begin{align}
\sum_k(-1)^k\binom{m}{k}\frac1{j\binom{n+k+j}{j}}
&=\sum_k(-1)^k\left[\binom{m-1}{k}+\binom{m-1}{k-1}\right]\frac1{j\binom{n+k+j}{j}}\tag1\\
&=\sum_k(-1)^k\binom{m-1}{k}\left[\frac1{j\binom{n+k+j}{j}}-\frac1{j\binom{n+k+j+1}{j}}\right]\tag2\\
&=\sum_k(-1)^k\binom{m-1}{k}\frac1{(j+1)\binom{n+k+j+1}{j+1}}\tag3\\
&=\sum_k(-1)^k\binom{m-m}{k}\frac1{(j+m)\binom{n+k+j+m}{j+m}}\tag4\\[3pt]
&=\frac1{(j+m)\binom{n+j+m}{j+m}}\tag5
\end{align}
$$
Explanation:
$(1)$: Pascal's Rule
$(2)$: distribute the sum
$\phantom{\text{(2):}}$ substitute $k\mapsto k+1$ in the right-hand sum
$\phantom{\text{(2):}}$ collect the sums
$(3)$: expand into factorials, subtract, and collect
$\phantom{\text{(3):}}$ note that $m$ has been decreased and $j$ has been increased
$(4)$: repeat the previous process $m$ times
$(5)$: only the $k=0$ term survives
Set $j=1$ and we get
$$
\sum_k(-1)^k\binom{m}{k}\frac1{n+k+1}=\frac{n!\,m!}{(n+m+1)!}\tag6
$$
Partial Fractions
Heaviside Method for Partial Fractions guarantees that we can write
$$
\frac{n!\,m!}{(n+m+1)!}=\frac{m!}{(n+1)(n+2)\cdots(n+m+1)}=\sum_{k=0}^m\frac{a_k}{n+k+1}\tag7
$$
and compute $a_k$ by multiplying both sides by $n+k+1$ and evaluating at $n=\color{#C00}{-k-1}$:
$$\require{cancel}
\scriptsize\frac{m!}{\underbrace{(\color{#C00}{(-k-1)}+1)\cdots(\color{#C00}{(-k-1)}+k)}_{(-1)^kk!}\cancel{(\color{#C00}{(-k-1)}+k+1)}\underbrace{(\color{#C00}{(-k-1)}+k+2)\cdots(\color{#C00}{(-k-1)}+m+1)}_{(m-k)!}}=a_k\tag8
$$
That is,
$$
a_k=(-1)^k\binom{m}{k}\tag9
$$
Thus, $(7)$ and $(9)$ give $(6)$.