By request, see here for an outline from first principles:
http://www.igt.uni-stuttgart.de/eiserm/lehre/2014/Topologie/Gale%20-%201-manifolds.pdf
EDIT: this link is now dead. The reference is
Gale, D. (1987). The classification of 1-manifolds: a take-home exam. The American Mathematical Monthly, 94(2), 170-175.
This proof proves that all topological 1-manifolds (without boundary) are homeomorphic to $\mathbb{R}$ or $S^1$. From this we get the corollary that all $1$-manifolds can be endowed with $C^{\infty}$ structures. In fact, it is true that all 1-manifolds are diffeomorphic to $\mathbb{R}$ or $S^1$. For this proof, my guess is that using integral curves/orientations is probably the easiest, though check Guilliman/Pollack for sure.
Additionally, there is another proof with more of an algebraic topology flavor using CW complexes found in Lee's Topological Manifolds, Theorem 5.27.