From the LES in homotopy groups for the pair $(S^2 \times S^2, S^2 \vee S^2)$, we have an exact sequence
$$\pi_4(S^2 \vee S^2) \to \pi_4(S^2 \times S^2) \to \pi_4(S^2 \times S^2, S^2 \vee S^2)\to \pi_3(S^2 \vee S^2) \to \pi_3(S^2 \times S^2)$$
Since we have $\pi_k(S^2 \times S^2)\cong \pi_k(S^2 ) \times \pi_k( S^2) \subset \pi_k(S^2 \vee S^2)$, the maps $\pi_k(S^2 \vee S^2) \to \pi_k(S^2 \times S^2)$ are surjective. It follows that $\pi_4(S^2 \times S^2)\to \pi_4(S^2 \times S^2, S^2 \vee S^2)$ is the zero map, giving us a short exact sequence
$$0 \to \pi_4(S^2 \times S^2, S^2 \vee S^2)\to \pi_3(S^2 \vee S^2) \to \pi_3(S^2 \times S^2) \to 0.$$
We want an element $\alpha \in \pi_3(S^2 \vee S^2)$ such that its composition with each projection $S^2 \vee S^2 \to S^2$ is nullhomotopic. These projections factor through $S^2 \times S^2$, so $\alpha$ lies in the kernel of the composition $\pi_3(S^2 \vee S^2) \to \pi_3(S^2 \times S^2) \overset{\sim}{\to} \pi_3(S^2) \times \pi_3(S^2)$. Thus it suffices to show that $\pi_4(S^2 \times S^2, S^2 \vee S^2)$ is nontrivial, since any nonzero element in its image in $\pi_3(S^2 \vee S^2)$ will work for us.
Here's where the hint comes in: Recall that $S^2 \times S^2$ has a cell structure with one $0$-cell, two $2$-cells, and one $4$-cell. The 3-skeleton is simply $S^2 \vee S^2$, so the boundary of the 4-cell is mapped into $S^2 \vee S^2$. Since $S^2 \vee S^2 \vee S^4$ is not homotopy equivalent to $S^2 \times S^2$, the 4-cell's attaching map is nontrivial, giving us the desired element of $\pi_3(S^2 \vee S^2)$.