Very Engaging Problem!!! I find this one to be 'mos 'def significant because it brings together a collection of essential facts about roots of unity into one example which can be stated in more or less elementary terms. For this reason I have written out my answer in terms of first principles, explaining each step as I go along, even at risk of re-deriving a few basic facts.
It is not necessary to employ guesswork here; indeed, all is unravelled logically from the stated hypothesis, as follows:
First off, recall that for a real polynomial $p(z) \in \Bbb R[z]$, $\lambda \in \Bbb C$ is a zero of $p(z)$ if and only if $\bar \lambda \in \Bbb C$ is also;
$p(\lambda) = 0 \Leftrightarrow p(\bar \lambda) = 0; \tag{1}$
(1) may be seen by writing
$p(z) = \sum_0^n p_i z^i, \tag{2}$
with each $p_i \in \Bbb R$; then
$\overline{p(\lambda)} = \overline{\sum_0^n p_i \lambda^i} = \sum_0^n \overline{p_i \lambda^i} = \sum_0^n \bar p_i \bar \lambda^i = p(\bar \lambda) \tag{3}$
since $\bar p_i = p_i \in \Bbb R$, $1 \le i \le n$. (1) then is an immediate consequence of (3). Note we have only used basic properties of complex conjugation here, viz. $\overline{a + b} = \bar a + \bar b$, $\overline{ab} = \bar a \bar b$, and $\bar a = a$ for $a \in \Bbb R$.
It follows from the above that if $\alpha + \alpha^2 + \alpha^4$ is a root of the real quadratic polynomial
$q(x) = z^2 + Az + B \in \Bbb R[z], \tag{4}$
the other zero must indeed be
$\overline{\alpha + \alpha^2 + \alpha^4} = \bar \alpha + \bar \alpha^2 + \bar \alpha^4. \tag{5}$
We further massage (5); observe that for any unimodular complex number $\beta$,
$\beta \bar \beta = \vert \beta \vert^2 = 1, \tag{6}$
whence
$\bar \beta = \beta^{-1}; \tag{6}$
exploiting this property in (5) yields
$\overline{\alpha + \alpha^2 + \alpha^4} = \alpha^{-1} + \alpha^{-2} + \alpha^{-4}. \tag{7}$
Next, we have
$\alpha^k \alpha^{7 - k} = \alpha^{k + (7 - k)} = \alpha^7 = 1 \tag{8}$
for any $k \in \Bbb Z$; thus
$\alpha^{-k} = (\alpha^k)^{-1} = \alpha^{7 - k}; \tag{9}$
now (7) becomes
$\overline{\alpha + \alpha^2 + \alpha^4} = \alpha^6 + \alpha^5 + \alpha^3; \tag{10}$
(7) presents the other root of $q(z)$ solely in terms of powers of $\alpha$.
Since $\alpha^7= 1$, we may write
$(\alpha - 1)(\sum_0^6 \alpha^i) = \alpha^7 - 1 = 0; \tag{11}$
since $\alpha \ne 1$, this yields
$\sum_0^6 \alpha^i = 0 \tag{12}$
or
$\sum_1^6 \alpha^i = -1, \tag{13}$
thus, by (10)
$(\alpha + \alpha^2 + \alpha^4) + \overline{\alpha + \alpha^2 + \alpha^4} = -1, \tag{14}$
from which we immediately conclude
$\Re(\alpha + \alpha^2 + \alpha^4) = -\dfrac{1}{2}; \tag{15}$
with
$\alpha = e^{(2\pi i / 7)} = \cos \dfrac{2\pi}{7} + i \sin \dfrac{2\pi}{7}, \tag{16}$
we easily see, using de Moivre's formula
$(\cos \theta + i\sin \theta)^n = \cos n\theta + i \sin n\theta, \tag{17}$
that
$\cos \dfrac{2\pi}{7} + \cos \dfrac{4\pi}{7} + \cos \dfrac{8\pi}{7} = -\dfrac{1}{2}. \tag{18}$
As for $A$ and $B$, setting
$\mu = \alpha + \alpha^2 + \alpha^4, \tag{19}$
we see that
$q(z) = (z - \mu)(z - \bar \mu) = z^2 - (\mu + \bar \mu)z + \mu \bar \mu; \tag{20}$
comparing (20) with (4) we find
$A = -(\mu + \bar \mu), \; B = \mu \bar \mu; \tag{21}$
so (14) directly indicates
$A = 1. \tag{22}$
To find $B$, we use $B = \mu \bar \mu$, with $\bar \mu$ given by (10), and $\alpha^7 = 1$:
$B = \mu \bar \mu = (\alpha + \alpha^2 + \alpha^4)(\alpha^3 + \alpha^5 + \alpha^6)$
$= \alpha^4 + \alpha^6 + 1 + \alpha^5 + 1 + \alpha + 1 + \alpha^2 + \alpha^4 = 3 + \sum_1^6 \alpha^i = 3 - 1 = 2. \tag{23}$
Finally, the sum
$\sin \dfrac{2\pi}{7} + \sin \dfrac{4\pi}{7} + \sin \dfrac{8\pi}{7} \tag{24}$
may be evaluated by recognizing it as the imaginary part of $\mu = \alpha + \alpha^2 + \alpha^4$, which is one of the two roots of
$q(z) = z^2 + Az + B = z^2 + z + 2; \tag{25}$
applying the quadratic formula to (25), we find the roots are
$\dfrac{1}{2}(-1 \pm \sqrt{1^2 - 4(2)}) = \dfrac{1}{2}(-1 \pm \sqrt{-7}) = -\dfrac{1}{2} \pm i\dfrac{\sqrt{7}}{2}; \tag{26}$
next, we observe that
$\sin \dfrac{2\pi}{7} + \sin \dfrac{4\pi}{7} + \sin \dfrac{8\pi}{7} > 0, \tag{27}$
since we may write
$\sin \dfrac{2\pi}{7} + \sin \dfrac{4\pi}{7} + \sin \dfrac{8\pi}{7} = \sin \dfrac{2\pi}{7} + \sin \dfrac{4\pi}{7} + \sin (\pi + \dfrac{\pi}{7})$
$= \sin \dfrac{2\pi}{7} + \sin \dfrac{4\pi}{7} - \sin \dfrac{\pi}{7} = \sin \dfrac{4\pi}{7} + (\sin \dfrac{2\pi}{7} - \sin \dfrac{\pi}{7}); \tag{28}$
inspecting (28), we note that
$\dfrac{\pi}{7}, \dfrac{2\pi}{7}, \dfrac{4\pi}{7} \in (0, \pi), \tag{29}$
hence
$\sin \dfrac{\pi}{7}, \sin \dfrac{2\pi}{7}, \sin \dfrac{4\pi}{7} > 0; \tag{30}$
furthermore,
$\dfrac{\pi}{7}, \dfrac{2\pi}{7} \in (0, \dfrac{\pi}{2}); \tag{31}$
since $\sin$ is strictly monotonically increasing on $(0, \pi/2)$, it follows that
$\sin \dfrac{2\pi}{7} - \sin \dfrac{\pi}{7} > 0; \tag{32}$
using (30), (32) in (28) shows that (27) binds; thus $\sin (2\pi /7) + \sin (4\pi /7) + \sin (8\pi / 7)$ corresponds to the root of (25) with positive imaginary part; that is
$\sin \dfrac{2\pi}{7} + \sin \dfrac{4\pi}{7} + \sin \dfrac{8\pi}{7} = \dfrac{\sqrt{7}}{2}; \tag{33}$
who would have thought? Not me, certainly, until, that is, I worked through this problem!
Nota Bene: How to generalize?