Here is a theorem about convergence of iterative methods for linear system in Burden and Faires' book "Numerical Analysis"
For any $x_0 \in \mathbb{R}^n$, the sequence defined by $x^k = Tx_{k-1} + c$ converges to the unique solution of $x = Tx + c$ if and only if the spectral radius of T is less than 1.
I understand that the iteration converges to a solution of $x = Tx + c$, but how do we know that a solution to $x = Tx + c$ is unique?