There are some convergent series whose exact sum can be evaluated. For instance:
$$\displaystyle\sum_{n=1}^{\infty}\dfrac{n}{(n+1)!}.$$
Observing that
$$\dfrac{n}{(n+1)!}=\dfrac{(n+1)-1}{(n+1)!}=\dfrac{1}{n!}-\dfrac{1}{(n+1)!}$$
the series telescopes. Therefore,
$$\displaystyle\sum_{n=1}^{\infty}\dfrac{n}{(n+1)!}=1-\underset{n\rightarrow\infty}{\lim}\dfrac{1}{(n+1)!}=1-0=1.$$
But in general it is a difficult task to find the exact sum, as you said.
Added: Unlike $\displaystyle\sum_{n=1}^{\infty }\frac{1}{n^{2}}$ whose sum equals $\dfrac{\pi ^{2}}{6}$, the series $\displaystyle\sum_{n=1}^{\infty }\dfrac{1}{n^{3}}$, although convergent, nobody knows a closed form in terms of other mathematical constants. This sum is therefore a mathematical constant in itself.
Added 2: Another example that uses integration and differentiation of the geometric series $$\sum_{n=1}^{\infty }x^{n}=\frac{x}{1-x},\qquad\left\vert x\right\vert <1$$ is
$$\sum_{n=1}^{\infty }\frac{n}{(n+1)e^{n}}=e\left( \log \frac{e-1}{e}+\frac{1%
}{e-1}\right) .$$
Added 3: From
$$\sum_{n=1}^{\infty }x^{n}=\frac{x}{1-x}\qquad\left\vert x\right\vert <1,$$
we get for $\left\vert x\right\vert <1$
$$\int \sum_{n=1}^{\infty }x^{n}dx=\sum_{n=1}^{\infty }\frac{1}{n+1}%
x^{n+1}=\int \frac{x}{1-x}dx=-x-\log \left\vert 1-x\right\vert .$$
Hence,
$$\sum_{n=1}^{\infty }\frac{1}{n+1}x^{n}=-1-\frac{1}{x}\log \left\vert
1-x\right\vert $$
Now if we diferentiate, we have
$$\sum_{n=1}^{\infty }\frac{n}{n+1}x^{n-1}=\frac{1}{x^{2}}\log \left\vert
1-x\right\vert -\frac{1}{x^{2}-x},$$
or equivalently
$$\sum_{n=1}^{\infty }\frac{n}{n+1}x^{n}=\frac{1}{x}\log \left\vert
1-x\right\vert -\frac{1}{x-1}\qquad\left\vert x\right\vert <1.$$
Finally for $x=e^{-1}$, we obtain
$$\sum_{n=1}^{\infty }\frac{n}{(n+1)e^{n}}=e\left( \log \frac{e-1}{e}+\frac{1%
}{e-1}\right) .$$