The inequality in question is obviously intimately related to Hadamard’s maximum determinant problem. So, I believe that the most natural construction of $A(n)$ is to make use of Hadamard matrices.
Given any $n\times n$ $\{-1,1\}$ matrix $H$, there is a well-known trick to obtain a $\{0,1\}$ matrix $A$ such that $\det(A)=\frac1{2^{n-1}}|\det(H)|$. First, turn the first row of $H$ into a rows of ones by multiplying columns of $H$ by $-1$ if necessary. Second, for every row $i>1$, add the first row to it and then divide it by $2$. As a result, we get a $\{0,1\}$ matrix. Finally, if the matrix has a negative determinant, interchange some two rows to negate the determinant.
It is also well-known that when $n$ is a power of $2$, Hadamard matrices of size $n$ can be constructed recursively (e.g. Sylvester's construction). Since the determinant of a Hadamard matrix is $\pm n^{n/2}$, it follows that whenever $n=2^m$, there exists a $\{0,1\}$ matrix $A(n)$ whose determinant is $\frac1{2^{n-1}}n^{n/2} = 2(\sqrt{n}/2)^n$.
Now, consider any natural number $n$. Let $n=\sum_{i=1}^k 2^{m_i}+r$, where $m_1>m_2>\cdots>m_k\ge3$ and $0\le r<8$ (convention: $\sum_{i=1}^k 2^{m_i}$ is an empty sum if $n<8$). Therefore, if we define $A(n)=A(2^{m_1})\oplus A(2^{m_2})\oplus\cdots\oplus A(2^{m_k})\oplus I_r$, then
$$
\det A(n) = 2^k\prod_{i=1}^k (\sqrt{2^{m_i}}/2)^{2^{m_i}} \ge \prod_{i=1}^k (\sqrt{2^3}/2)^{2^{m_i}} \ge \sqrt{2}^{n-r} > \frac1{16}\sqrt{2}^n.
$$