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Note that
\begin{align}&\color{#66f}{\large%
\int_{0}^{\infty}{\ln\pars{1 + x^{2}} \over x^{2}}\,\dd x}
=\half\int_{0}^{\infty}{\ln\pars{1 + x} \over x^{3/2}}\,\dd x
=\half\int_{1}^{\infty}\pars{x - 1}^{-3/2}\,\,\ln\pars{x}\,\dd x
\qquad\pars{1}
\end{align}
We evaluate the integral, in the RHS, by performing the contour integral
$$
\oint_{\gamma}\pars{z - 1}^{-3/2}\,\,\ln\pars{z}\,\dd z
$$
along the path $\ds{\gamma}$ depicted below:

which shows two branch cuts. Namely:
\begin{align}
\begin{array}{rclrcll}
\pars{z - 1}^{-3/2} & = &\verts{z - 1}^{-3/2}
\exp\pars{-\,{3 \over 2}\,\,{\rm Arg}\pars{z - 1}\ic}\,, & z & \not= & 1 \,,
& \phantom{-}0 < \,{\rm Arg}\pars{z - 1} < 2\pi
\\[5mm]
\ln\pars{z}&=&\ln\pars{\verts{z}} + \ic\,{\rm Arg}\pars{z}\,,& z &\not = & 0\,,
& -\pi < \,{\rm Arg}\pars{z} < \pi
\end{array}
\end{align}
Obviously, the integral along $\ds{\gamma}$ vanishes out because there are not any poles inside the contour. For simplicity, we omit the contribution of the arcs $\ds{C_{R}}$, of radius $\ds{R}$, and the 'small' semicircles, of radius $\ds{\epsilon}$, around $\ds{z=0}$ and $\ds{z=1}$: They don't yield any contribution in the limits $\ds{R\ \to\ \infty\,,\ \epsilon\ \to\ 0^{+}}$. Then,
\begin{align}
0&=\oint_{\gamma}\pars{z - 1}^{-3/2}\,\,\ln\pars{z}\,\dd z
=\overbrace{\int_{1}^{\infty}\pars{x - 1}^{-3/2}\ln\pars{x}\,\dd x}
^{\ds{\mbox{along}\ \dsc{C_{++}}}}
\\[5mm]&+\overbrace{%
\int_{-\infty}^{0}\pars{1 - x}^{-3/2}\expo{-3\pi\ic/2}
\bracks{\ln\pars{x} + \ic\pi}\,\dd x}
^{\ds{\mbox{along}\ \dsc{C_{-+}}}}\ +\ \overbrace{%
\int^{-\infty}_{0}\pars{1 - x}^{-3/2}\expo{-3\pi\ic/2}
\bracks{\ln\pars{x} - \ic\pi}\,\dd x}
^{\ds{\mbox{along}\ \dsc{C_{--}}}}
\\[5mm]&+\overbrace{\int^{1}_{\infty}\pars{x - 1}^{-3/2}
\expo{-3\pi\ic}\ln\pars{x}\,\dd x}
^{\ds{\mbox{along}\ \dsc{C_{+-}}}}\ =\
2\int_{1}^{\infty}\pars{x - 1}^{-3/2}\ln\pars{x}\,\dd x
\\[5mm]&\phantom{=}+2\pi\ic\expo{-3\pi\ic/2}\int_{-\infty}^{0}
\pars{1 - x}^{-3/2}\,\dd x
=2\int_{1}^{\infty}\pars{x - 1}^{-3/2}\ \ln\pars{x}\,\dd x
-\left.{4\pi \over \root{1 - x}}\,\right\vert_{\, x\ \to\ -\infty}^{\, x\ =\ 0}
\\[5mm]&=2\int_{1}^{\infty}\pars{x - 1}^{-3/2}\ \ln\pars{x}\,\dd x - 4\pi
\quad\imp\quad
\boxed{\ds{\quad\int_{1}^{\infty}\pars{x - 1}^{-3/2}\ \ln\pars{x}\,\dd x
=2\pi\quad}}
\end{align}
Replacing this result in expression $\pars{1}$, we'll find:
\begin{align}&\color{#66f}{\large%
\int_{0}^{\infty}{\ln\pars{1 + x^{2}} \over x^{2}}\,\dd x}
=\color{#66f}{\Large\pi}
\end{align}