Theorem 1
Let $f$ be a measurable function on $(a,b)$. Then the function
$$
g_n(x)=\sup\left\{f(x+h):h\in(0,\frac{1}{n})\cap(0,b-x)\right\}
$$
is measurable.
Proof
Fix $c\in\mathbb{R}$. We want to prove that the set $A=\{x\in(a,b):g_n(x)>c\}$ is measurable, then $g_n$ will be measurable. Let $x_0\in A$, then there exist $h_0\in(0,\frac{1}{n})\cap(0,b-x_0)$ such that $f(x_0+h_0)>c$. Define
$$
\delta_1=\frac{1}{2}\left(\min\left(\frac{1}{n},b-x_0\right)-h_0\right)\qquad
\delta_2=\frac{1}{2}\left(\min\left(\frac{1}{n},b-x_0\right)+h_0\right)
$$
then for all $x\in(x_0-\delta_1, x_0+\delta_2)$ we have $x_0+h_0\in\{x+h:h\in(0,\frac{1}{n})\cap(0,b-x)\}$. As the consequence $g_n(x)\geq f(x_0+h_0)>c$, so $x\in A$ for all $x\in(x_0-\delta_1, x_0+\delta_2)$. This means that $A$ is open, hence measurable.
Theorem 2
Let $f$ be a mesurable function on $(a,b)$ then the set
$$
A=\{x\in(a,b):\exists f'(x)\in\mathbb{R}\}
$$
is measurable.
Proof
Extend $f$ by equalities: $f(x)=f(a)$ for $x<a$ and $f(x)=f(b)$ for $x>b$. For each $c\in\mathbb{R}$ consider measurable function $\phi(x)=f(x)-cx$. From theorem 1 it follows that
$$
\psi_n(x)=\sup\left\{\phi(x+h):h\in(0,\frac{1}{n})\cap(0,b-x)\right\}
$$
is measurable. Then we have measurable function
$$
\psi_n(x)-\phi(x)=\sup\left\{\phi(x+h)-\phi(x):h\in(0,\frac{1}{n})\cap(0,b-x)\right\}.
$$
Hence the set
$$
B=\{x\in(a,b):\psi_n(x)-\phi(x)>0\}=
$$
$$
\left\{x\in(a,b):\sup\left\{\frac{f(x+h)-f(x)}{h}:h\in(0,\frac{1}{n})\cap(0,b-x)\right\}>c\right\}
$$
is measurable. Since $c\in\mathbb{R}$ is arbitrary then the functions
$$
f_n(x)=\sup\left\{\frac{f(x+h)-f(x)}{h}:h\in(0,\frac{1}{n})\cap(0,b-x)\right\}
$$
are measurable. So we conclude that the function
$$
\overline{f}'_+(x)=\overline{\lim\limits_{h\to 0+}}\frac{f(x+h)-f(x)}{h}=\lim\limits_{n\to\infty}f_n(x)
$$
is also measurable. Similarly, we can prove that functions
$$
\underline{f}'_+(x)=\underline{\lim\limits_{h\to 0+}}\frac{f(x+h)-f(x)}{h}=\lim\limits_{n\to\infty}f_n(x)
$$
$$
\overline{f}'_-(x)=\overline{\lim\limits_{h\to 0-}}\frac{f(x+h)-f(x)}{h}=\lim\limits_{n\to\infty}f_n(x)
$$
$$
\underline{f}'_-(x)=\underline{\lim\limits_{h\to 0-}}\frac{f(x+h)-f(x)}{h}=\lim\limits_{n\to\infty}f_n(x)
$$
are mesurable. Finally, the set $A=\{x\in(a,b):\exists f'(x)\in\mathbb{R}\}$ is measurable because
$$
A=\{x\in(a,b):\overline{f}'_+(x)=\underline{f}'_+(x)=\overline{f}'_-(x)=\underline{f}'_-(x)\in\mathbb{R}\}
$$