If one is allowed to use the values $a$ and $b$ of the eigenvalues, and if $a\ne b$, then one gets
$$\mathrm e^{tA}=\frac{\mathrm e^{at}-\mathrm e^{bt}}{a-b}A+\frac{a\mathrm e^{bt}-b\mathrm e^{at}}{a-b}I,$$
No need here for series expansion or "Jordan canonical form, change of basis matrix, etc.", the substitute being to work directly in the two-dimensional vector space $\mathbb C[A]$, with basis $\{I,A\}$.
To prove the formula above, consider the function $$u(t)=\mathrm e^{At}.$$ The facts that $u'(t)=A\mathrm e^{At}$, $u''(t)=A^2\mathrm e^{At}$, and $A^2-(a+b)A+ab=0$, together yield $$u''(t)-(a+b)u'(t)+abu(t)=0.$$ This (matrix-valued) differential equation is solved by $$u(t)=\mathrm e^{at}U+\mathrm e^{bt}V,$$ for some well chosen (matrices) $U$ and $V$. These are such that $$U+V=u(0)=I,\qquad aU+bV=u'(0)=A.$$ Solving this $2\times2$ Cramer system for $(U,V)$ yields the formula stated at the beginning of this post.
In the end, the method only requires the (seemingly inescapable) step to solve for $(a,b)$ the system
$$a+b=\mathrm{tr}(A),\qquad ab=\mathrm{det}(A).$$
Example 1: If $A=\begin{pmatrix} 0&9 \\ -1&0 \end{pmatrix}$, then $a+b=0$ and $ab=9$ hence one can choose $a=3\mathrm i$ and $b=-3\mathrm i$, then $a-b=6\mathrm i$, $\mathrm e^{at}-\mathrm e^{bt}=2\mathrm i\sin(3t)$ and $a\mathrm e^{bt}-b\mathrm e^{at}=6\mathrm i\cos(3t)$ hence
$$\mathrm e^{tA}=\tfrac13\sin(3t)A+\cos(3t)I=\begin{pmatrix} \cos(3t)&3\sin(3t) \\ -\tfrac13\sin(3t)&0\cos(3t)\end{pmatrix}.$$
Example 2: If $A=\begin{pmatrix} 3 & 5\cr-5 & -3\end{pmatrix}$, then $a+b=0$ and $ab=16$ hence one can choose $a=4\mathrm i$ and $b=-4\mathrm i$, then $a-b=8\mathrm i$, $\mathrm e^{at}-\mathrm e^{bt}=2\mathrm i\sin(4t)$ and $a\mathrm e^{bt}-b\mathrm e^{at}=8\mathrm i\cos(4t)$ hence
$$\mathrm e^{tA}=\tfrac14\sin(4t)A+\cos(4t)I=\begin{pmatrix} \cos(4t)+\tfrac34\sin(4t)&\tfrac54\sin(4t) \\ -\tfrac54\sin(4t)&\cos(4t)-\tfrac34\sin(4t)\end{pmatrix}.$$
Edit: As noted by @abel in a comment, Putzer algorithm can be used to compute $\mathrm e^{tA}$. For $A$ of size $2\times2$ with eigenvalues $a$ and $b$, the algorithm says that $$\mathrm e^{tA}=r(t)I+s(t)(A-aI),$$ where the (scalar) functions $r$ and $s$ solve the differential system $$r'(t)=ar(t),\quad r(0)=1,\quad s'(t)=bs(t)+r(t),\quad s(0)=0.$$ This yields $r(t)=\mathrm e^{at}$ and, since $a\ne b$, $(a-b)s(t)=\mathrm e^{at}-\mathrm e^{bt}$, thus $$\mathrm e^{tA}=\mathrm e^{at}I+\frac{\mathrm e^{at}-\mathrm e^{bt}}{a-b}\,(A-aI),$$ which is equivalent to the formula we proved above.