To show that the function in Riemann-integrable you have to show that it is bounded and has at most a countable set of discontinuities in the interval you are integrating. But this is the case of an improper integral, since $1/x$ is not defined in $x = 0$, you have to follow the criterions for improper integrals, which is the existence of the limit $\lim_{x\rightarrow 0} \int_x^1 \frac{1}{x} dx$ and its finiteness.
Assuming that by $[\frac{1}{x}]$ you mean the integer part of x (the closest integer less then or equal to x), we can always assume that $[\frac{1}{x}]$ is zero, because if x less than or greater than zero, you always have a number less than one, the integer part of which is always zero. So your integral is the same as $\int_0^1 \frac{1}{x} dx - \int_0^1 [\frac{1}{x}] dx = \int_0^1 \frac{1}{x} dx$, which does not converge on that interval.
EDIT: promt comments showed that I'm way over my head...Sorry for the wrong answer.