HINT: Take a sequence of partitions which alternate between including $0$ and not including $0$ while having their size go to $0$ (the most natural choice will do, since $0$ is the midpoint of the interval); pick your "tag" appropriately in the ones that do not include $0$ so that the sum gives you one value, and see what you get when the partition does include $0$. With some appropriate choices, you'll get a sequence that does not converge, showing that the limit does not exist.
To prove the function is Riemman-Stieltjes integrable relative to $a$, break up the integral into two interals, possibly redefining $f$ and $a$ at a single point in one or both of them, so that you can use the standard formula for Riemman-Stieltjes when the functions are "nice".