Be careful with this answer: it's very possible I messed something up Yes, I did! See comments. Here goes: we want $$\mathbb{P}(X \leqslant a, Y \leqslant b) = \mathbb{P}(X \leqslant a)\mathbb{P}(Y \leqslant a)$$
Suppose first we have sequences of real numbers $a_j \rightarrow a, b_j \rightarrow b$. Then I claim first that $$a \leqslant A, b \leqslant B \Longleftrightarrow \forall n, \exists i | \forall j > i: a_j \leqslant A + \frac{1}{n}, b_j \leqslant B + \frac{1}{n}$$
Applying this criterion to $X_i(\omega) \rightarrow X(\omega), Y_i(\omega) \rightarrow Y(\omega)$ for each $\omega$ (throwing away a set of measure 0), we get $$\{ X \leqslant a, Y \leqslant b \} = \bigcap_n \bigcup_{i \geqslant 0} \bigcap_{j \geqslant i} \{ X_j \leqslant a + \frac{1}{n}, Y_j \leqslant b + \frac{1}{n} \}$$
When evaluating the probability of this, we can drag the $\mathbb{P}$ across each $\cap$ and $\cup$ since the relevant events (everything to the right of said operation) are nested, hence we get $$\mathbb{P}(X \leqslant a, Y \leqslant b) = \lim_n \lim_i \lim_{j \geqslant i} \mathbb{P}(X_j \leqslant a + \frac{1}{n}, Y_j \leqslant b + \frac{1}{n})$$By independence of $X_j$ and $Y_j$, we can rewrite this as $$\lim_n \lim_i \lim_{j \geqslant i} \mathbb{P}(X_j \leqslant a + \frac{1}{n})\mathbb{P}(Y_j \leqslant b + \frac{1}{n}) $$$$= (\lim_n \lim_i \lim_{j \geqslant i} \mathbb{P}(X_j \leqslant a + \frac{1}{n}))(\lim_n \lim_i \lim_{j \geqslant i} \mathbb{P}(Y_j \leqslant b + \frac{1}{n})) = \mathbb{P}(X \leqslant a)\mathbb{P}(Y \leqslant b) $$