This is true because you can define an isomorphism between the elements of $S$ and $G$ in the obvious way. That is, a bijective function $f\colon S\rightarrow G$ such that $f(a)f(b)=f(a\bot b)$. If $S$ with the defined binary operation is isomorphic to a group, then you should easily be able to show that all the group axioms hold on $S$. As a quick example I'll show that all $a\in S$ have a right inverse.
Let $c=(f(a))^{-1}$. $f$ is a bijection and so there exists a $b\in S$ such that $f(b)=c$. Now, $f(a)(f(a))^{-1}=1$ which means that $f(a)c=1$. $f$ is an isomorphism and so $f^{-1}$ is also an isomorphism, hence $f^{-1}(f(a))\bot f^{-1}(c)=f^{-1}(f(a).c)=f^{-1}(1)$ which means that $a\bot b=1$ and so $a$ has a right inverse.
You can show the rest of the axioms hold.