This depends on what kind of hexadecimal representation you're looking for; if you just want the numbers in base $16$ with the sign, drop the sign and convert them. If you want to convert the binary numbers to base $16$, use the following neat trick:
Since $16 = 2^4$, every four bits correspond to a single hexadecimal digit. So what you should do is pad the number with zeros (say you had $1110101110$, take $001110101110$), then group it into four digit groups ($0011~1010~1110$), then use the following table to translate:
$$ 0000 \to 0 $$
$$ 0001 \to 1 $$
$$ 0010 \to 2 $$
$$ 0011 \to 3 $$
$$ 0100 \to 4 $$
$$ 0101 \to 5 $$
$$ 0110 \to 6 $$
$$ 0111 \to 7 $$
$$ 1000 \to 8 $$
$$ 1001 \to 9 $$
$$ 1010 \to A $$
$$ 1011 \to B $$
$$ 1100 \to C $$
$$ 1101 \to D $$
$$ 1110 \to E $$
$$ 1111 \to F $$
For example, $0011~1010~1110 \to 3AE$
As for two's complement, the rule is $\tilde{} n = -n -1$, that is, for $8$ digit numbers $11111111$ represents $0-1 = -1$. Every number with a leading $1$ is negative, so the smallest is $10000000 = \tilde{} 01111111 = -127 - 1 = -128 $, and the largest is $01111111 = 127$.