The right hand side of your displayed equation should be $\sum(x,x_n)T(x_n)$. With this correction, your argument shows that any $y\in Y$ has a representation $y=\sum\alpha_i Tx_i$. To show that $(Tx_i)$ is, in fact, a (Schauder) basis of $Y$, you need to show that this representation is unique. So here, you have to prove that if $y=\sum\alpha_iTx_i$, then necessarily, $\alpha_i=(x,x_i)$ for every $i$. This is easily done using the fact that $T^{-1}$ is continuous and the fact that $(x_i)$ is a basis of $X$.
In fact, you can show considerably more: not only is $(Tx_i)$ a basis of $Y$; but also that the basis $(Tx_i)$ is equivalent to the basis $(x_i)$. That is, $\sum\alpha_i x_i$ converges if and only if $\sum\alpha_iTx_i$ converges. It follows then that $(Tx_i)$ is an unconditional basis of $Y$ and that $\sum\alpha_iTx_i$ converges if and only if $(\alpha_i)\in\ell_2$. A normalized basis satisfying the latter condition is called a Riez basis.
(Incidentally, one can show, using the parallelogram law, that a normalized basis of a separable Hilbert space is unconditional if and only if it is a Riez basis.)
So, $(Tx_i)$ shares one important property that orthonormal bases possess. But, $(Tx_i)$ is not necessarily orthonormal or even orthogonal. This follows from the fact that if one "peturbs" a basis $(x_n)$ by a sufficiently small amount, it remains a basis equivalent to $(x_n)$. More precisely: if $(x_n)$ is a normalized basis of $X$ with basis constant $K$ and if $(y_n)$ is a sequence from $X$ with $\sum\Vert x_n-y_n\Vert\le 1/2K$, then $(y_n)$ is a basis of $X$ which is equivalent to $(x_n)$ (c.f. Lindenstrauss and Tzafriri, Classical Banach Spaces I, proposition 1.a.9.).