I you don't necessarily want compact manifolds, in dimension $3$ and up there are manifolds which are contractible (i.e., homotopy equivalent to a point), but not homeomorphic to$\mathbb{R}^n$. See, for example, the Whitehead manifold.
I you insist on compact simply connected manifolds, I don't know of too many examples. For example, in Kamerich's thesis "Transitive transformation groups on products of two spheres", he proves
The homogeneous space $(Sp(24)\times Sp(2))/(Sp(23)\times \Delta Sp(1) \times Sp(1))$ given by the embedding $(A,p,q)\mapsto \big(\operatorname{diag}(A,p), \operatorname{diag}(p,q)\big)$ where $Sp(n)$ denotes $n\times n$ quaternionic unitary matrices is homotopy equivalent but not homeomorphic to $S^{95}\times S^4$. Further, this is best result possible in the sense that replacing $24$ and $23$ with smaller numbers always gives examples which are not homotopy equivalent to any product of spheres.
Onishik's book "The Topology of Transformation Groups" pg. 275 contains more details.