By describing all motion with respect to the center-of-mass frame, we can restrict our attention to $ \mathbb{R}^{2} $ only. In what follows, $ \mathbf{q}_{1},\mathbf{q}_{2}: \mathbb{R} \to \mathbb{R}^{n} $ denote the displacement functions of two particles with respect to the center-of-mass frame, where the center-of-mass is fixed at the origin of $ \mathbb{R}^{n} $.
For central-force motion involving only two particles, the trajectories $ \mathbf{q}_{1} $ and $ \mathbf{q}_{2} $ are seen to lie strictly within a $ 2 $-dimensional subspace $ \Pi $ of $ \mathbb{R}^{n} $. If the affine vectors $ {\dot{\mathbf{q}}_{1}}(0) $ and $ {\dot{\mathbf{q}}_{2}}(0) $ are oriented such that they do not simultaneously point toward/away from the origin, then $ \Pi $ is uniquely determined.
What I have done above is to choose an isometry $ T \in \mathbf{O}(n,\mathbb{R}) $ in order to obtain
$$
T[\Pi] \subseteq \mathbb{R}^{2} \times \underbrace{\{ 0 \} \times \cdots \times \{ 0 \}}_{\text{$ n - 2 $ times}}.
$$
This allows us to shift our focus to $ \mathbb{R}^{2} $. Clearly, the chosen isometrically-linear coordinate transformation does not affect the physics that is being described by the equations of motion specified by the OP above.
With this in mind, note that for $ \alpha = 3 $, what we have is basically the well-studied Coulomb Collision Problem. Depending on the orientation of the affine vectors $ {\dot{\mathbf{q}}_{1}}(0) $ and $ {\dot{\mathbf{q}}_{2}}(0) $, the trajectories lie in
I find it rather interesting that the derivation of the Rutherford Scattering Formula in atomic physics relies upon this fact.
For $ \alpha \in \mathbb{R}_{> 0} \setminus \{ 3 \} $ in general, we no longer have a nice description of the trajectories involved. However, one can easily use an energy-conservation argument to prove that trajectories cannot collide, and this is precisely what Jorge has described in his solution.