I won't produce more formulas, but I can tell you why they aren't the same:
Given a parametric representation $t\mapsto \gamma(t)$ of a curve $\gamma$ in ${\mathbb R}^3$ the velocity vector $\gamma'(t)={d\gamma(t)\over dt}$ encodes information about the speed $\|\gamma'(t)\|$ of the moving point $\gamma(t)$ as well as information about the tangential direction of the curve $\gamma$ at the point $P=\gamma(t)$. The normalized vector $$\tau:=\gamma'(t)/\|\gamma'(t)\|=\dot\gamma$$
is the unit tangent vector to $\gamma$ at $P$.
The $\dot{}$ has the following meaning: Among all parametric representations ("timetables") of one and the same geometric curve $\gamma$ there is a distinguished one: the representation with respect to arc length $s$ along $\gamma$. This special representation is distinguished by the property $\|\dot\gamma\|=\left\|{d\gamma(s)\over ds}\right\|\equiv1$, and differentiation with respect to this special parameter is denoted by a $\cdot\ $.
The acceleration vector $\gamma''(t)$ encodes the infinitesimal change of the velocity vector $\gamma'(t)$. This change has a tangential component which is related to a change of speed, and a normal component which is related to a change of direction, and therewith to curvature. When you normalize this vector to $n^?:=\gamma''(t)/\|\gamma''(t)\|$ you get a certain unit vector incorporating information about speed change and direction change. Its physical or geometrical meaning is unclear.
On the other hand the vector $\tau:=\gamma'(t)/\|\gamma'(t)\|=\dot\gamma$ contains only information about the tangential direction of $\gamma$ at the point $P=\gamma(t)$, but no information about the speed with which the moving point passes the point $P$ . The vectors $\tau'={d\tau\over dt}$ and $\dot \tau={d\tau\over ds}$ therefore only contain information about the change of direction along $\gamma$, whereby $\tau'$ measures this change in relation to time and $\dot\tau$ in relation to arc length. The relation between $\dot\tau$ and $\tau'$ is given by
$$\dot\tau ={d\tau\over ds}={d\tau\over dt}\bigg/{ds\over dt}={\tau'\over\|\gamma'\|}\ .$$
In any case $\dot\tau$ is geometrically more relevant than $\tau'$; in fact $\|\dot\tau\|$ is the curvature of $\gamma$ at the point $P$.
The vector $n:={\dot\tau\over\|\dot\tau\|}$ is a unit vector pointing into the direction into which $\tau$ changes to. It is automatically orthogonal to $\tau$ since we took care to keep $\tau$ of unit length at all times.