Suppose the determinant is zero, then one of its rows is linearly dependent on the preceeding ones, say:
$$\left(e^{\lambda_1x_i}\,,\,e^{\lambda_2x_i}\,,\ldots,e^{\lambda_nx_i}\right)=\sum_{k=1}^{i-1}a_k\left(e^{\lambda_1x_k}\,,\,e^{\lambda_2x_k}\,,\ldots,e^{\lambda_nx_k}\right)\,\,,\,\,a_k\in\Bbb R$$
From the above, we get for each $\,1\leq t\leq n\,$:
$$\sum_{k=1}^{i-1}a_ke^{\lambda_tx_k}=e^{\lambda_tx_i}\Longrightarrow\Phi(\lambda_t):=\sum_{k=1}^{i-1}a_ke^{\lambda_tx_k}-e^{\lambda_tx_i}=0\Longrightarrow$$
$$ \Phi'(\lambda_t)=\sum_{k=1}^{i-1}a_kx_ke^{\lambda_tx_k}-x_ie^{\lambda_tx_i}=0$$
But then
$$\sum_{k=1}^{i-1}a_kx_ke^{\lambda_tx_k}=x_ie^{\lambda_tx_i}=x_i\sum_{k=1}^{i-1}a_ke^{\lambda_tx_k}\Longrightarrow$$
$$\sum_{k=1}^{i-1}a_k(x_k-x_i)e^{\lambda_tx_k}=0\Longrightarrow a_1=a_2=...=a_{i-1}=0$$
since $\,(x_k-x_i)e^{\lambda_tx_k}\neq 0\,\,\,,\,\forall\,\,1\leq k\leq i-1$ ...