For something explicit, consider the Schwarz-Christoffel mapping. Together with $z\mapsto \frac{i-iz}{z+1}$ this produces a map $f$ of the open unit disc via upper halfplane to a regular hexagon. With suitable adjustments you can achieve $f(0)=0$ and $f'(0)>0$. Then the restriction of $f$ to $\{z\mid 0< \arg z<\frac\pi3, 0<|z|<1\}$ will be the mapping you want (including that $f(z)$ tends to the vertices if $z$ tends to a vertex; this follows by symmetry).
On the other hand, $f$ cannot be extended conformally to the vertices themselves.
To elaborate on the "symmetry handwaving" above:
Let $D$ be the open unit disc and $X$ the open hexagon.
We know that the automorphisms of $D$ have the form $\phi_{u,a}\colon z\mapsto u\frac{z-a}{1-\bar a z}$ with $|u|=1$ and $|a|<1$.
If we have an arbitrary biholomorphic $f_1\colon D\to X$, let $b=f_1^{-1}(0)$.
Then $f_2:=f_1\circ \phi_{1,-b}$ is also biholomorphic $D\to X$, but this time we know $0\mapsto 0$.
Let $c=f_2'(0)$. Then $c\ne0$ and $f_3:=f_2\circ \phi_{\frac{|c|}c,0}$ is also biholomorphic $D\to X$ and as promised we have $f_3(0)=0$, $f_3'(0)>0$.
Assume $f_4\colon D\to X$ is biholomorphic with $f_4(0)=0$ and $f_4'(0)>0$. Then $f_3^{-1}\circ f_4\colon D\to D$ is an automorphism, i.e. it is some $\phi_{u,a}$. From $\phi(0)=0$ we conclude $a=0$ and then from $\phi'_{u,a}(0)>0$ we conclude $u=1$. It follows that the automorphism is the identity, i.e. $f_4=f_3$. There is exactly one biholomorphic map $D\to X$ that maps $0\mapsto 0$ and has positive real derivative at $0$.
Now observe that $f_5\colon z\mapsto \overline{f_3(\bar z)}$ is also a biholomorphic map $D\to X$ with $f_5(0)=0$ and $f_5'(0)>0$. Hence $f_5=f_3$, which implies that $f_3(z)$ is real if $z$ is real. In fact, injectivity and positive derivative at $0$ impliy that $f_3$ maps $[0,1)$ to itself monotonuously.
Also observe that $f_6\colon z\mapsto e^{-\frac\pi3} f_3(e^{\frac\pi3} z)$ has $f_6(0)=0$, $f_6'(0)>1$, hence $f_6=f_3$ and we conclude that $f_3$ maps the line $e^{\frac\pi3}\cdot [0,1)$ to itself.
In summary, $f_3$ maps the region bounded by the straight line from $0$ to $1$, the straight line from $0$ to $e^{\frac\pi3}$ and the circular arc from $0$ to $e^{\frac\pi3}$ biholomorphically to the triangle with vertices $0$, $1$ and $e^{\frac\pi3}$.