Let $u = \sin^2(x)$. Then $\frac{\mathrm{d}x}{\tan(x)} = \frac{\cos(x)}{\sin(x)} \mathrm{d}x = \frac{d\sin(x)}{\sin(x)} = \frac{1}{2}\frac{\mathrm{d}u}{u}$, $\ln(\sin(x)) = \frac{1}{2}\ln(u)$ and $\ln(\cos(x)) = \frac{1}{2} \ln(1-u)$:
$$
\int_0^{\pi/2} \frac{\ln(\sin(x)) \ln(\cos(x))}{\tan(x)} \mathrm{d} x = \frac{1}{8} \int_0^{1} \frac{\ln u}{u} \cdot \ln(1-u) \mathrm{d} u = \left.\frac{1}{8} \frac{\mathrm{d}^2}{\mathrm{d} s \mathrm{d} t} \int_0^1 u^{s-1} (1-u)^{t-1} \mathrm{d}u \right|_{s\to 0^+,t=1} = \left.\frac{1}{8} \frac{\mathrm{d}^2}{\mathrm{d} s \mathrm{d} t} \frac{\Gamma(s) \Gamma(t)}{\Gamma(s+t)} \right|_{s\to 0^+,t=1}
$$
First differentiate with respect to $t$ and substitute $t=1$:
$$
\left.\frac{1}{8} \frac{\mathrm{d}}{\mathrm{d} s} \frac{\Gamma(s)}{\Gamma(s+1)}\left( \psi(1) - \psi(s+1)\right) \right|_{s\to 0^+} = \left.\frac{1}{8} \frac{\mathrm{d}}{\mathrm{d} s} \frac{\left( \psi(1) - \psi(s+1)\right) }{s} \right|_{s\to 0^+}
$$
Using Taylor series expansion for the digamma function $\psi(s)$ we have:
$$
\frac{\left( \psi(1) - \psi(s+1)\right) }{s} = -\zeta(2) + \zeta(3) s + \mathcal{o}(s)
$$
Hence the value of the integral is:
$$
\int_0^{\pi/2} \frac{\ln(\sin(x)) \ln(\cos(x))}{\tan(x)} \mathrm{d} x = \frac{1}{8} \zeta(3)
$$
Alternatively you could use $$\frac{\ln(1-u)}{u} = -\sum_{k=0}^\infty \frac{u^k}{k+1}$$ and integrate term-wise: $$\int_0^1 u^k \ln(u) \mathrm{d} u \stackrel{u=\exp(-t)}{=} \int_0^\infty t \exp(-t(k+1)) \mathrm{d} t = -\frac{1}{(k+1)^2}$$ which yields the result immediately.