Write $\mathbb C=\mathbb R[x]/\langle x^2+1\rangle$ for one of the copies. Then, using a universal property of tensor products,
$$
\mathbb C\otimes_{\mathbb R} \mathbb C
\;\approx\;
\mathbb R[x]/\langle x^2+1\rangle \otimes_{\mathbb R}\mathbb C
\;\approx\; \mathbb C[x]/\langle (x+i)(x-i)\rangle
\;\approx\; \mathbb C[x]/\langle x+i\rangle \oplus
\mathbb C[x]/\langle x-i\rangle
$$
the last isomorphism via Sun-Ze's theorem (a.k.a. "Chinese Remainder Theorem"). That last isomorphism can be made explicit by choice of polynomials $A(x),B(x)$ such that $A(x)\cdot (x+i) + B(x)\cdot (x-i)=1$.
Edit: this treats "right" $\mathbb C$-algebra, but/and reversing the roles gives the same outcome as "left" algebra.