If you are willing to put bounds on your integral, it is possible to compute that $$\int_0^1 x^x\,dx = \sum_{n=1}^\infty \frac{(-1)^{n-1}}{n^n}.$$ Indeed, if you start like nbubis suggests, and make the substitution $u = -\log x$, you get that $$\int_0^1 x^x\,dx = \sum_{k=0}^\infty \frac{1}{k!}\int_0^1x^k(\log x)^k\,dx = \sum_{k=0}^\infty \frac{(-1)^k}{k!}\int_0^\infty e^{u(k+1)}u^k\,du$$$$ = \sum_{k=0}^\infty \frac{(-1)^k}{k!}\frac{1}{(k+1)^k}\int_0^\infty e^{u(k+1)}[(k+1)u]^k\,du.$$ If you then make the substitution $t = (k+1)u$ this becomes $$\sum_{k=0}^\infty \frac{(-1)^k}{k!}\frac{1}{(k+1)^k}\int_0^\infty e^tt^k\,dt = \sum_{k=0}^\infty \frac{(-1)^k}{(k+1)!}\frac{1}{(k+1)^k}\Gamma(k+1),$$ where $\Gamma$ is the usual Gamma function. Since $\Gamma(k+1) = k!$, the final expression is $$ \sum_{k=0}^\infty \frac{(-1)^k}{(k+1)^{k+1}} = \sum_{n=1}^\infty \frac{(-1)^{n-1}}{n^n}.$$ Similarly you can derive $\int_0^1 x^{-x}\,dx = \sum_{n=1}^\infty n^{-n}$. In don't think any further simplification is possible.