As @Cameron Williams has pointed out, you can write both of these as quadratic equations of a trigonometric function of $\theta_r.$
For equation (1), make the substitution $\cos\theta_r=\pm\sqrt{1-\sin^2\theta_r}$ and multiply through by $\sin\theta_r$ to get
$$e-m_t\sin\theta_r=\pm\sqrt{1-\sin^2\theta_r}.$$
Squaring both sides and setting equal to zero, we get
$$(m_t^2+1)\sin^2\theta_r-2em_t\sin\theta_r+(e^2-1)=0.$$
Solving for $\sin\theta_r$ using the Quadratic Formula gives
$$\sin\theta_r=\frac{em_t\pm\sqrt{m_t^2-e^2+1}}{m_t^2+1},$$
upon which you can use the inverse sine to extract $\theta_r.$
For equation (2), a similar trick will work. But as I suggested in the comments, I will use double angle formulas. Once I get to the quadratic form, I will leave it up to you to solve.
First multiplying through by $2\sin\theta_r\cos\theta_r,$ and then using the identities
- $\sin2\theta_r=2\sin\theta_r\cos\theta_r$
- $\cos2\theta_r=\cos^2\theta_r-\sin^2\theta_r,$ and
- $\cos^2\theta_r=\dfrac{1+\cos2\theta_r}{2}$
we get
$$m_t\sin2\theta_r=\frac{e^2}{2}(1+\cos2\theta_r)-\cos2\theta_r.$$
Now multiplying through by 2, once again using the Pythagorean Identity $\sin2\theta_r=\pm\sqrt{1-\cos^2 2\theta_r},$ and squaring both sides, we get
$$4m_t^2(1-\cos^2 2\theta_r)=e^4+2e^2(e^2-1)\cos2\theta_r+(e^2-1)^2\cos^2 2\theta_r,$$
which is a quadratic equation in $\cos 2\theta_r$ that I will leave you to solve.