My attempt: a combination of my comment and Shai's comment.
A partition means a partition of n using only 1,2,3,4,5,6.
Number of ways to get to 101: Number of partitions of 101.
Number of ways to get to 102: partitions of 96 + partitions of 97... + partitions of 100. Since we can have 96+6, 97+5, ...100+2.
...
Number of ways to get to 106: Partitions of 100. Since we can get to 106 only by adding to 100 then rolling 6.
A partition of n will be the nth coefficient x in $\prod_{k=0}^6 \frac{1}{1-x^k}$ using the geometric series. But an easier observation is that $a_n = a_{n-1}+a_{n-2}+a_{n-3}+a_{n-4}+a_{n-5}+a_{n-6}$. Using this
Number of ways to get to 101 is $a_{101}=a_{100}+a_{99}+a_{98}+a_{97}+a_{96}+a_{95}$
Number of ways to get to 102 is $a_{100}+a_{99}+a_{98}+a_{97}+a_{96}$
...
Number of ways to get to 106 is $a_{100}$
Since $a_n > 0$ we see that 101 will occur the most frequently.